General safety term · Glossary
Flash Point
Verified vs OSHA sources · 2026-10-05
The lowest temperature at which a liquid gives off enough vapor to form an ignitable mixture with air near its surface. It is the key property GHS uses to sort flammable liquids into categories — the lower the flash point, the more easily the liquid ignites.
Also known as: flashpoint, FP
On this page
Flash Point at a glance
- The lower the flash point, the more easily a liquid ignites.
- Flash point + boiling point together set the GHS flammable-liquid category (1–4).
- Gasoline's flash point is about −43°C (−45°F); diesel's sits close to the 60°C line that separates Category 3 from Category 4, and varies by grade — read the value from Section 9 of the SDS.
- Listed in Section 9 of the SDS; it drives storage, ventilation, and ignition-source rules.
In plain English
The temperature at which a liquid starts giving off enough vapor to catch fire if a spark or flame is near. A low flash point (like gasoline) means it can ignite at everyday temperatures; a high flash point (like diesel) means it has to be heated first.
What the rule says
“Flammable liquid means a liquid having a flash point of not more than 93 °C (199.4 °F).”
In context
An industrial-hygiene, exposure-control, or program-management concept that applies across OSHA standards and workplaces.
Where this is written in OSHA's rules
- 29 CFR 1910.1200 App B.6Read on eCFR / OSHA.gov
Example
Acetone has a flash point of about −20°C, so its vapors ignite well below room temperature — GHS Flammable Liquid Category 2. Diesel sits close to the line that separates Category 3 from Category 4: a grade whose SDS gives 55°C is Category 3, one at 62°C is Category 4. Same drum-on-a-jobsite picture, very different ignition risk — and only the measured value decides the category.
Why it matters
Flash point decides how a liquid must be stored, ventilated, and kept away from ignition sources — and its GHS category, label, and signal word all flow from it. Misclassifying a low-flash-point liquid, or storing it like a high-flash-point one, is both a fire risk and a HazCom labeling violation.
Flash point vs. autoignition vs. boiling point
Flash point is the lowest temperature at which vapors ignite when an external spark or flame is applied. Autoignition temperature is where it ignites on its own with no spark — much higher. Boiling point is where the liquid turns to vapor. GHS uses flash point and boiling point together to set the category.
GHS flammable-liquid categories by flash point (FP) and boiling point (BP)
| Category | Flash point | Boiling point | Example |
|---|---|---|---|
| 1 (most hazardous) | < 23°C (73.4°F) | ≤ 35°C (95°F) | Diethyl ether, pentane |
| 2 | < 23°C (73.4°F) | > 35°C (95°F) | Acetone, ethanol |
| 3 | ≥ 23°C and ≤ 60°C | — | Diesel, kerosene |
| 4 | > 60°C and ≤ 93°C | — | Heavier fuel oils |
Flash Point: frequently asked questions
- What is the difference between flash point and fire point?
- Flash point is the lowest temperature at which a liquid's vapor briefly ignites when an ignition source is applied. Fire point is the slightly higher temperature at which the vapor keeps burning for at least five seconds. GHS classification is based on flash point.
- What flash point makes a liquid 'flammable' under GHS?
- Under OSHA's GHS-aligned HazCom standard, a flammable liquid is one with a flash point of not more than 93°C (199.4°F). A flash point below 23°C combined with a low boiling point puts it in the most hazardous Category 1.
- Where do I find a chemical's flash point?
- In Section 9 (Physical and chemical properties) of its Safety Data Sheet. The resulting GHS flammable category appears in Section 2.
Related terms
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Governing OSHA standards
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Administrative ControlsChanges to how and when work is done — job rotation, scheduling, safe work practices, housekeeping, training, and signage — that reduce a worker's exposure without altering the hazard itself. They are the fourth tier of the hierarchy of controls, below engineering controls and above PPE.
Biological Exposure Index (BEI)An ACGIH guidance value for interpreting biological monitoring results — the concentration of a chemical (or its metabolite) measured in a worker's blood, urine, or exhaled breath. A BEI represents the level most likely found in a healthy worker whose inhalation exposure was at the TLV, so it measures the dose the body actually absorbed, not just what's in the air.
California Proposition 65California's Safe Drinking Water and Toxic Enforcement Act of 1986. It requires businesses to warn Californians before exposing them to any of the ~900+ listed chemicals known to the state to cause cancer, birth defects, or other reproductive harm, and prohibits discharging those chemicals into drinking-water sources. It's a California law, but it reaches nearly any product sold there.
CAS NumberA unique numerical identifier assigned by the Chemical Abstracts Service (a division of the American Chemical Society) to every distinct chemical substance. It has the format of up to seven digits, a dash, two digits, a dash, and a final check digit (e.g., 67-64-1 for acetone). Because chemical names vary, the CAS number is the unambiguous global key used on SDSs, inventories, and regulations.
Ceiling LimitAn exposure limit that must not be exceeded at any instant during the workday — the strictest type of OSHA exposure limit. In OSHA's Z-tables it is marked with a “C” before the value. Unlike an 8-hour TWA (an average) or a 15-minute STEL, a ceiling applies to a single moment.
Chemical CompatibilityWhether two or more chemicals can be safely stored or used near each other without reacting dangerously — releasing heat, toxic gas, or fire. Incompatible chemicals must be physically separated (segregated) in storage. Each chemical's incompatibilities are listed in Section 10 of its SDS, and compatibility drives storage layout and spill response.
Sources & verification
- 29 CFR 1910.1200 App B.6 (eCFR / OSHA.gov)
- OSHA — Appendix B to §1910.1200: Physical Criteria (Mandatory)
- 29 CFR 1910.106 — Flammable liquids (eCFR)
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
Put Flash Point into practice
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