General safety term · Glossary
Vapor Pressure
Verified vs OSHA sources · 2026-10-05
The pressure a substance's vapor exerts when it's in equilibrium with its own liquid (or solid) at a given temperature — a measure of how readily it evaporates. The higher the vapor pressure, the more volatile the chemical, and the more vapor it puts into the air, raising the potential for inhalation exposure and flammable-atmosphere buildup. It's listed in Section 9 of every SDS.
Also known as: vapour pressure
On this page
Vapor Pressure at a glance
- A measure of volatility — how readily a liquid evaporates.
- Higher vapor pressure → more vapor in the air → greater inhalation and fire risk.
- Increases with temperature (a warm solvent evaporates faster).
- Reported in Section 9 of the SDS (in mmHg, kPa, or psi at a stated temperature).
In plain English
How eager a liquid is to turn into vapor. High vapor pressure (like acetone) means it evaporates fast and fills the air with fumes; low vapor pressure (like motor oil) means it barely evaporates. More vapor in the air means more to breathe — and more that can ignite.
What the source says, in summary
Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid at a given temperature; the higher the vapor pressure, the more volatile the substance and the greater its potential to produce airborne exposure.
In context
An industrial-hygiene, exposure-control, or program-management concept that applies across OSHA standards and workplaces.
Where this is written in OSHA's rules
- 29 CFR 1910.1200 App DRead on eCFR / OSHA.gov
Example
Acetone has a high vapor pressure (~184 mmHg at 20 °C), so it evaporates quickly and its vapors accumulate fast in a poorly ventilated room — driving both inhalation exposure and a flammable atmosphere. Motor oil's vapor pressure is near zero, so it produces almost no vapor at room temperature.
Why it matters
Vapor pressure predicts how much of a liquid becomes breathable, ignitable vapor — so it's central to ventilation design, respirator decisions, and fire prevention. A high-vapor-pressure solvent can build a hazardous or explosive atmosphere fast in a confined space, which is why it's a key Section 9 property to check.
Vapor pressure vs. flash point
They're related but different. Vapor pressure is how much vapor a liquid gives off (its volatility) at a temperature. Flash point is the temperature at which that vapor becomes ignitable. A high vapor pressure and a low flash point together signal a chemical that both evaporates readily and ignites easily.
Vapor pressure and volatility
| Vapor pressure | Behavior | Example |
|---|---|---|
| High | Evaporates readily; higher inhalation & fire risk | Acetone, gasoline |
| Moderate | Evaporates at a moderate rate | Water, ethanol |
| Low / near zero | Barely evaporates at room temperature | Motor oil, glycerin |
Vapor Pressure: frequently asked questions
- What does vapor pressure tell you?
- How readily a substance evaporates. A high vapor pressure means it's volatile and produces a lot of vapor — increasing inhalation exposure and the risk of a flammable atmosphere. A low vapor pressure means little evaporation.
- Where do I find vapor pressure on an SDS?
- In Section 9 (Physical and chemical properties), usually given in mmHg or kPa at a stated temperature such as 20 °C or 25 °C.
- What is the difference between vapor pressure and flash point?
- Vapor pressure is how much vapor a liquid gives off (volatility); flash point is the temperature at which that vapor can ignite. A volatile liquid with a low flash point is both fast to evaporate and easy to ignite.
Related terms
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Governing OSHA standards
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An arc flash is the sudden release of thermal energy from an electrical arc fault — a short circuit that jumps through the air between energized parts. The arc can reach temperatures over 35,000°F (nearly four times the surface of the sun), causing severe burns, igniting clothing, and driving an explosive pressure wave known as the arc blast. OSHA sets no single “arc-flash standard”: the analysis method — the arc-flash boundary, incident energy, and arc-rated PPE — comes from the NFPA 70E consensus standard, which OSHA enforces through its electrical-PPE rules (29 CFR 1910.335, 1910.269) and the General Duty Clause.
Action LevelAn airborne concentration of a substance — typically half the PEL — at which certain provisions of an OSHA standard kick in (such as exposure monitoring, training, and medical surveillance), even though it is below the legal exposure limit. For respirable crystalline silica the action level is 25 µg/m³ as an 8-hour TWA, half the 50 µg/m³ PEL.
Administrative ControlsChanges to how and when work is done — job rotation, scheduling, safe work practices, housekeeping, training, and signage — that reduce a worker's exposure without altering the hazard itself. They are the fourth tier of the hierarchy of controls, below engineering controls and above PPE.
Biological Exposure Index (BEI)An ACGIH guidance value for interpreting biological monitoring results — the concentration of a chemical (or its metabolite) measured in a worker's blood, urine, or exhaled breath. A BEI represents the level most likely found in a healthy worker whose inhalation exposure was at the TLV, so it measures the dose the body actually absorbed, not just what's in the air.
California Proposition 65California's Safe Drinking Water and Toxic Enforcement Act of 1986. It requires businesses to warn Californians before exposing them to any of the ~900+ listed chemicals known to the state to cause cancer, birth defects, or other reproductive harm, and prohibits discharging those chemicals into drinking-water sources. It's a California law, but it reaches nearly any product sold there.
CAS NumberA unique numerical identifier assigned by the Chemical Abstracts Service (a division of the American Chemical Society) to every distinct chemical substance. It has the format of up to seven digits, a dash, two digits, a dash, and a final check digit (e.g., 67-64-1 for acetone). Because chemical names vary, the CAS number is the unambiguous global key used on SDSs, inventories, and regulations.
Ceiling LimitAn exposure limit that must not be exceeded at any instant during the workday — the strictest type of OSHA exposure limit. In OSHA's Z-tables it is marked with a “C” before the value. Unlike an 8-hour TWA (an average) or a 15-minute STEL, a ceiling applies to a single moment.
Chemical CompatibilityWhether two or more chemicals can be safely stored or used near each other without reacting dangerously — releasing heat, toxic gas, or fire. Incompatible chemicals must be physically separated (segregated) in storage. Each chemical's incompatibilities are listed in Section 10 of its SDS, and compatibility drives storage layout and spill response.
Sources & verification
- 29 CFR 1910.1200 App D (eCFR / OSHA.gov)
- OSHA — Chemical Hazards and Toxic Substances
- NIOSH Pocket Guide to Chemical Hazards (physical data)
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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