GHS / HazCom term · Glossary
Corrosive to Metals
Verified vs OSHA sources · 2026-10-05
A GHS physical-hazard class for chemicals that, by chemical action, will materially damage or even destroy metals. It is a single category (Category 1), determined by corrosion-rate testing on steel and aluminum, and uses the corrosion pictogram (GHS05) with the hazard statement H290. It is a separate hazard from skin corrosion, even though both use GHS05.
Also known as: metal corrosive
On this page
Corrosive to Metals at a glance
- A physical hazard (damage to metals) — distinct from skin corrosion (a health hazard).
- Single category (Category 1); corrosion rate > 6.25 mm/year on steel or aluminum at 55 °C.
- Pictogram GHS05 (corrosion); hazard statement H290, “May be corrosive to metals.”
- Drives packaging choice and storage segregation — it can degrade its own container.
In plain English
A chemical that eats metal. It's classed as a physical hazard (it attacks materials and containers), separate from skin corrosion (which attacks you) — even though both share the same corrosion symbol.
What the rule says
“A chemical which is corrosive to metals means a chemical which by chemical action will materially damage, or even destroy, metals.”
In context
A classification or labeling concept from the UN Globally Harmonized System, adopted into US law through OSHA's Hazard Communication Standard (29 CFR 1910.1200) and its appendices.
Where this is written in OSHA's rules
- 29 CFR 1910.1200 App B.16Read on eCFR / OSHA.gov
Example
Concentrated hydrochloric acid attacks steel, so it's classified corrosive to metals — label pictogram GHS05 and H290, “May be corrosive to metals.” That hazard also dictates packaging: it must be stored in a compatible (non-metal or lined) container that the acid won't eat through.
Why it matters
A metal-corrosive can destroy its own container, piping, and equipment — causing leaks and secondary hazards. Overlooking the class can lead to the wrong packaging and a HazCom labeling gap; it's also why SDS Section 10 (incompatibilities) matters for storage.
Corrosive to metals vs. skin corrosion
Both use the corrosion pictogram (GHS05), but they're different hazards. “Corrosive to metals” is a physical hazard — it damages metal (H290). “Skin corrosion” is a health hazard — it burns skin and eyes (H314). A chemical can be one, the other, or both.
“Corrosion” — two different GHS hazards (both GHS05)
| Hazard | What it attacks | Class · H-code |
|---|---|---|
| Corrosive to metals | Metals — containers, equipment | Physical hazard · H290 |
| Skin corrosion | Skin and eyes | Health hazard · H314 |
Corrosive to Metals: frequently asked questions
- Is 'corrosive to metals' the same as 'skin corrosion'?
- No. Corrosive to metals is a physical hazard — chemical damage to metals (H290). Skin corrosion is a health hazard — burning of skin and eyes (H314). They share the GHS05 corrosion pictogram but are classified separately, and a chemical may have either or both.
- How is 'corrosive to metals' determined?
- By a corrosion-rate test: a substance is Category 1 if it corrodes steel or aluminum at a rate exceeding 6.25 mm per year at a test temperature of 55 °C.
- What hazard statement is used?
- H290, “May be corrosive to metals,” shown with the corrosion pictogram (GHS05).
Related terms
Free tools for this
Governing OSHA standards
More GHS terms
A GHS health-hazard class for the harmful effects that follow a single dose, several doses within 24 hours, or a 4-hour inhalation exposure. Chemicals are sorted into categories by route (oral, dermal, inhalation) using LD50/LC50 cut-offs — Category 1 is the most toxic. OSHA's HazCom standard uses Categories 1–4.
Aspiration HazardA GHS health-hazard class for chemicals that can be fatal if swallowed and then enter the airways — directly or by vomiting — causing chemical pneumonia or lung injury. Thin, low-viscosity hydrocarbons (gasoline, kerosene, lamp oil) are the classic example. It is Category 1, with the health-hazard pictogram (GHS08) and signal word “Danger.”
CarcinogenicityA GHS health-hazard class for chemicals that cause cancer or increase its incidence. GHS (and OSHA's HazCom standard) sorts carcinogens into Category 1A (known human carcinogen), 1B (presumed, from animal evidence), and Category 2 (suspected). Carcinogens carry the health-hazard pictogram (GHS08) and a hazard statement such as H350 (“May cause cancer”).
Chemicals Under PressureA physical-hazard class added by OSHA's 2024 HCS update (aligning with GHS Revision 7) for liquids or solids pressurized with a gas, held in pressure receptacles other than aerosol dispensers and not classified as gases under pressure. It is categorized by the flammability of its contents and always carries the gas-cylinder pictogram (GHS04) for the pressure hazard.
ClassificationThe process of evaluating the available scientific evidence for a chemical against the GHS criteria to decide whether it is hazardous and, if so, the hazard class and category of each effect. Classification is the first step in HazCom — its result determines every label element (pictogram, signal word, hazard and precautionary statements) and SDS content.
Desensitized ExplosivesA physical-hazard class added by OSHA's 2024 HCS update (GHS Revision 7) for solid or liquid explosives that have been phlegmatized — wetted or diluted — to suppress their explosive properties for safe transport and storage. It has four categories based on the corrected burning rate, and uses the flame pictogram (GHS02), not the exploding-bomb.
Globally Harmonized System (GHS)An internationally agreed framework created by the United Nations (first adopted in 2003) that standardizes how chemical hazards are classified and communicated — using common hazard classes, pictograms, signal words (Danger / Warning), and coded hazard (H) and precautionary (P) statements on labels and safety data sheets. The US adopted GHS into law through OSHA's 2012 Hazard Communication Standard update.
GHS Revision 7The 7th revision of the UN Globally Harmonized System, which OSHA adopted in its 2024 update to the Hazard Communication Standard (with selected elements of Revision 8). It adds new hazard classes — desensitized explosives and chemicals under pressure — folds pyrophoric and chemically unstable gases into flammable gases, and updates label and SDS provisions. The final rule was effective July 19, 2024, with phased compliance dates.
Sources & verification
- 29 CFR 1910.1200 App B.16 (eCFR / OSHA.gov)
- OSHA — Appendix B to §1910.1200: Physical Criteria (Mandatory)
- UNECE GHS — Part 2: Physical Hazards
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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