General safety term · Glossary
pH
Verified vs OSHA sources · 2026-10-05
A measure of how acidic or alkaline (basic) a water-based solution is, on a scale from 0 to 14. A pH of 7 is neutral, below 7 is acidic, and above 7 is basic. The scale is logarithmic — each whole number is a tenfold change in acidity. In chemical safety, extreme pH matters: GHS treats a pH of 2 or lower, or 11.5 or higher, as a signal that a substance may be corrosive to skin. It's reported in Section 9 of a Safety Data Sheet.
Also known as: potential of hydrogen, acidity/alkalinity
On this page
pH at a glance
- Scale 0–14: 7 is neutral, < 7 acidic, > 7 basic (alkaline).
- Logarithmic — pH 3 is ten times more acidic than pH 4, a hundred times more than pH 5.
- GHS: pH ≤ 2 or ≥ 11.5 flags potential skin corrosivity.
- Reported in SDS Section 9 (Physical and Chemical Properties).
In plain English
A 0–14 number telling you how acidic or basic a liquid is. 7 is neutral (pure water), lower is acidic (like battery acid), higher is basic (like bleach or lye). The far ends — very low or very high — can burn skin.
What the source says, in summary
A substance with a pH of 2 or less, or a pH of 11.5 or greater, may be presumed to be corrosive to skin (extreme pH being one indicator considered in classification).
In context
An industrial-hygiene, exposure-control, or program-management concept that applies across OSHA standards and workplaces.
Where this is written in OSHA's rules
- 29 CFR 1910.1200Read on eCFR / OSHA.gov
- 29 CFR 1910.1200 App A.2Read on eCFR / OSHA.gov
Example
A drain cleaner with a pH of about 13 (strongly basic, lye-based) and a rust remover with a pH near 1 (strongly acidic) both fall outside the 2–11.5 window — so both are flagged as potentially skin-corrosive and carry the GHS05 corrosion pictogram.
Why it matters
pH is a fast first read on whether a chemical can chemically burn skin and eyes. Because GHS uses the 2 and 11.5 thresholds as corrosion indicators, the pH in SDS Section 9 helps confirm why a product is labeled corrosive and what PPE and first-aid (copious water flushing) it demands.
pH alone doesn't fully decide corrosivity
Extreme pH is an indicator, not the whole story. A solution's “acid or alkali reserve” (buffering capacity) affects how corrosive it actually is — a weakly buffered extreme pH may be less aggressive than a strongly buffered one. That's why GHS uses pH as one input to classification, alongside other data, rather than the sole test.
The pH scale and safety significance
| pH range | Character | Safety note |
|---|---|---|
| 0–2 | Strongly acidic | Potentially corrosive (≤ 2) |
| 3–6 | Weakly acidic | Generally less corrosive |
| 7 | Neutral | Water |
| 8–11 | Weakly to moderately basic | Generally less corrosive |
| 11.5–14 | Strongly basic | Potentially corrosive (≥ 11.5) |
pH: frequently asked questions
- What does pH measure?
- How acidic or basic a water-based solution is, on a 0–14 scale. 7 is neutral, below 7 is acidic, and above 7 is basic. The scale is logarithmic, so each unit is a tenfold change.
- What pH is considered corrosive?
- Under GHS, a pH of 2 or lower, or 11.5 or higher, is treated as an indicator that a substance may be corrosive to skin — though buffering capacity is also considered.
- Where do I find a chemical's pH?
- In Section 9 (Physical and Chemical Properties) of its Safety Data Sheet, when pH is applicable to the product.
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Sources & verification
- 29 CFR 1910.1200 (eCFR / OSHA.gov)
- 29 CFR 1910.1200 App A.2 (eCFR / OSHA.gov)
- OSHA — 1910.1200 (Hazard Communication / SDS)
- OSHA — GHS Skin Corrosion/Irritation Criteria (App A)
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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