GHS / HazCom term · Glossary
Desensitized Explosives
Verified vs OSHA sources · 2026-10-05
A physical-hazard class added by OSHA's 2024 HCS update (GHS Revision 7) for solid or liquid explosives that have been phlegmatized — wetted or diluted — to suppress their explosive properties for safe transport and storage. It has four categories based on the corrected burning rate, and uses the flame pictogram (GHS02), not the exploding-bomb.
Also known as: phlegmatized explosives
On this page
Desensitized Explosives at a glance
- New in OSHA's 2024 HCS (GHS Revision 7); not in the 2012 standard.
- Four categories based on the corrected burning rate of the desensitized substance.
- Uses the flame pictogram (GHS02) — the residual hazard is fire, not mass explosion.
- Hazard statements: H206 (Cat 1), H207 (Cat 2–3), H208 (Cat 4).
In plain English
Explosives that have been deliberately “tamed” — soaked or diluted so they won't mass-explode — so they can be shipped and stored more safely. They still burn and can be dangerous, which is why GHS gives them their own hazard class with a fire warning.
What the source says, in summary
Desensitized explosives are solid or liquid explosive chemicals which are phlegmatized to suppress their explosive properties in such a manner that they do not mass explode and do not burn too rapidly and therefore may be exempted from the hazard class “Explosives”.
In context
A classification or labeling concept from the UN Globally Harmonized System, adopted into US law through OSHA's Hazard Communication Standard (29 CFR 1910.1200) and its appendices.
Where this is written in OSHA's rules
- 29 CFR 1910.1200 App B.17Read on eCFR / OSHA.gov
Example
Wetted nitrocellulose or a phlegmatized organic peroxide is shipped as a desensitized explosive: stabilized so it won't mass-detonate, but still a fire/projection risk. A Category 1 example carries the flame pictogram (GHS02) and H206, “Desensitized explosive; fire, blast or projection hazard.”
Why it matters
Because this class is new in 2024, materials previously labeled only as explosives or peroxides may need reclassification and relabeling by the phased compliance dates. The flame (not exploding-bomb) pictogram also signals the actual residual hazard — fire — to responders.
Desensitized explosives vs. explosives
Explosives (GHS01, exploding-bomb) can mass-explode. Desensitized explosives have been wetted or diluted specifically to prevent mass explosion, leaving a fire/projection hazard — so they get the flame pictogram (GHS02) and their own class, distinct from the explosives class.
GHS desensitized explosives categories
| Category | Hazard statement (H-code) |
|---|---|
| 1 | H206 — Fire, blast or projection hazard |
| 2 / 3 | H207 — Fire or projection hazard |
| 4 | H208 — Fire hazard |
Desensitized Explosives: frequently asked questions
- What does 'desensitized' mean for an explosive?
- It has been phlegmatized — wetted with water/alcohol or diluted with another substance — to suppress its explosive properties so it won't mass-explode during normal handling, transport, and storage, leaving mainly a fire/projection hazard.
- Why do desensitized explosives use the flame pictogram, not the exploding bomb?
- Because desensitization removes the mass-explosion hazard; the remaining hazard is fire (and possible projection). GHS therefore assigns the flame pictogram (GHS02) and statements H206–H208 rather than the explosives class (GHS01).
- Is this a new OSHA hazard class?
- Yes — it was added in OSHA's 2024 Hazard Communication Standard update aligning with GHS Revision 7, and did not exist under the 2012 standard.
Related terms
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Governing OSHA standards
More GHS terms
A GHS health-hazard class for the harmful effects that follow a single dose, several doses within 24 hours, or a 4-hour inhalation exposure. Chemicals are sorted into categories by route (oral, dermal, inhalation) using LD50/LC50 cut-offs — Category 1 is the most toxic. OSHA's HazCom standard uses Categories 1–4.
Aspiration HazardA GHS health-hazard class for chemicals that can be fatal if swallowed and then enter the airways — directly or by vomiting — causing chemical pneumonia or lung injury. Thin, low-viscosity hydrocarbons (gasoline, kerosene, lamp oil) are the classic example. It is Category 1, with the health-hazard pictogram (GHS08) and signal word “Danger.”
CarcinogenicityA GHS health-hazard class for chemicals that cause cancer or increase its incidence. GHS (and OSHA's HazCom standard) sorts carcinogens into Category 1A (known human carcinogen), 1B (presumed, from animal evidence), and Category 2 (suspected). Carcinogens carry the health-hazard pictogram (GHS08) and a hazard statement such as H350 (“May cause cancer”).
Chemicals Under PressureA physical-hazard class added by OSHA's 2024 HCS update (aligning with GHS Revision 7) for liquids or solids pressurized with a gas, held in pressure receptacles other than aerosol dispensers and not classified as gases under pressure. It is categorized by the flammability of its contents and always carries the gas-cylinder pictogram (GHS04) for the pressure hazard.
ClassificationThe process of evaluating the available scientific evidence for a chemical against the GHS criteria to decide whether it is hazardous and, if so, the hazard class and category of each effect. Classification is the first step in HazCom — its result determines every label element (pictogram, signal word, hazard and precautionary statements) and SDS content.
Corrosive to MetalsA GHS physical-hazard class for chemicals that, by chemical action, will materially damage or even destroy metals. It is a single category (Category 1), determined by corrosion-rate testing on steel and aluminum, and uses the corrosion pictogram (GHS05) with the hazard statement H290. It is a separate hazard from skin corrosion, even though both use GHS05.
Globally Harmonized System (GHS)An internationally agreed framework created by the United Nations (first adopted in 2003) that standardizes how chemical hazards are classified and communicated — using common hazard classes, pictograms, signal words (Danger / Warning), and coded hazard (H) and precautionary (P) statements on labels and safety data sheets. The US adopted GHS into law through OSHA's 2012 Hazard Communication Standard update.
GHS Revision 7The 7th revision of the UN Globally Harmonized System, which OSHA adopted in its 2024 update to the Hazard Communication Standard (with selected elements of Revision 8). It adds new hazard classes — desensitized explosives and chemicals under pressure — folds pyrophoric and chemically unstable gases into flammable gases, and updates label and SDS provisions. The final rule was effective July 19, 2024, with phased compliance dates.
Sources & verification
- 29 CFR 1910.1200 App B.17 (eCFR / OSHA.gov)
- OSHA — Hazard Communication Standard 2024 Final Rule
- OSHA — Appendix B to §1910.1200: Physical Criteria (Mandatory)
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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