GHS / HazCom term · Glossary
Organic Peroxide
Verified vs OSHA sources · 2026-10-05
A liquid or solid organic chemical containing the unstable bivalent –O–O– (peroxide) structure. Organic peroxides are thermally unstable and can undergo exothermic self-accelerating decomposition — meaning they generate their own heat and can accelerate toward fire or explosion, sometimes without any external ignition. GHS classifies them into seven types (A through G) by how violently they react; many require temperature control during storage.
Also known as: peroxide (organic)
On this page
Organic Peroxide at a glance
- Contains the reactive –O–O– peroxide bond; thermally unstable.
- Can undergo exothermic self-accelerating decomposition (self-heating toward fire/explosion).
- Seven GHS types, A (most hazardous — can detonate/deflagrate as packaged) through G (least).
- Many require temperature control; also sensitive to heat, shock, and friction.
In plain English
A reactive chemical with a weak “–O–O–” bond that makes it prone to breaking down and releasing heat on its own. Push it with warmth, shock, or friction and it can catch fire or explode. Many must be kept cold to stay stable.
What the rule says
“Organic peroxide means a liquid or solid organic chemical which contains the bivalent -0-0- structure and as such is considered a derivative of hydrogen peroxide, where one or both of the hydrogen atoms have been replaced by organic radicals. The term organic peroxide includes organic peroxide mixtures containing at least one organic peroxide. Organic peroxides are thermally unstable chemicals, which may undergo exothermic self-accelerating decomposition.”
In context
A classification or labeling concept from the UN Globally Harmonized System, adopted into US law through OSHA's Hazard Communication Standard (29 CFR 1910.1200) and its appendices.
Where this is written in OSHA's rules
- 29 CFR 1910.1200 App B.15Read on eCFR / OSHA.gov
Example
Benzoyl peroxide and MEKP (methyl ethyl ketone peroxide), used as curing agents for fiberglass resins, are organic peroxides. They carry the GHS02 flame pictogram — and the most reactive types also carry GHS01 (exploding bomb) — and are stored cool and away from accelerators to prevent runaway decomposition.
Why it matters
Organic peroxides can decompose and ignite or detonate without an external ignition source, which makes their storage temperature and segregation genuinely life-safety critical. Because Types A and B can behave like explosives, GHS assigns them the exploding-bomb pictogram — so classifying the correct type drives both the label and the storage regime.
Organic peroxide vs. oxidizer
They're related but distinct hazard classes. An oxidizer supplies oxygen that intensifies the burning of other materials. An organic peroxide is itself an unstable fuel-plus-oxygen molecule that can decompose and burn or explode on its own. An organic peroxide is not simply “an oxidizer” — it gets its own GHS class and criteria.
GHS organic peroxide types (A–G)
| Type | Behavior |
|---|---|
| A | Can detonate or deflagrate rapidly as packaged |
| B | Has explosive properties; won't fully detonate but can deflagrate |
| C–F | Progressively less violent decomposition / reduced explosive behavior |
| G | Thermally stable; no explosive/deflagration hazard (least hazardous) |
Organic Peroxide: frequently asked questions
- What is an organic peroxide?
- A liquid or solid organic chemical containing the unstable –O–O– bond. It's thermally unstable and can undergo exothermic self-accelerating decomposition, making it prone to fire or explosion, sometimes without external ignition.
- What do the organic peroxide types A–G mean?
- They rank decomposition violence: Type A can detonate or deflagrate as packaged (most hazardous), through Type G, which is thermally stable with no explosive or deflagration hazard (least hazardous).
- Why do some organic peroxides need refrigeration?
- Because heat accelerates their decomposition. Keeping them below their control temperature slows the self-accelerating reaction and prevents a runaway that could cause fire or explosion.
Related terms
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Governing OSHA standards
More GHS terms
A GHS health-hazard class for the harmful effects that follow a single dose, several doses within 24 hours, or a 4-hour inhalation exposure. Chemicals are sorted into categories by route (oral, dermal, inhalation) using LD50/LC50 cut-offs — Category 1 is the most toxic. OSHA's HazCom standard uses Categories 1–4.
Aspiration HazardA GHS health-hazard class for chemicals that can be fatal if swallowed and then enter the airways — directly or by vomiting — causing chemical pneumonia or lung injury. Thin, low-viscosity hydrocarbons (gasoline, kerosene, lamp oil) are the classic example. It is Category 1, with the health-hazard pictogram (GHS08) and signal word “Danger.”
CarcinogenicityA GHS health-hazard class for chemicals that cause cancer or increase its incidence. GHS (and OSHA's HazCom standard) sorts carcinogens into Category 1A (known human carcinogen), 1B (presumed, from animal evidence), and Category 2 (suspected). Carcinogens carry the health-hazard pictogram (GHS08) and a hazard statement such as H350 (“May cause cancer”).
Chemicals Under PressureA physical-hazard class added by OSHA's 2024 HCS update (aligning with GHS Revision 7) for liquids or solids pressurized with a gas, held in pressure receptacles other than aerosol dispensers and not classified as gases under pressure. It is categorized by the flammability of its contents and always carries the gas-cylinder pictogram (GHS04) for the pressure hazard.
ClassificationThe process of evaluating the available scientific evidence for a chemical against the GHS criteria to decide whether it is hazardous and, if so, the hazard class and category of each effect. Classification is the first step in HazCom — its result determines every label element (pictogram, signal word, hazard and precautionary statements) and SDS content.
Corrosive to MetalsA GHS physical-hazard class for chemicals that, by chemical action, will materially damage or even destroy metals. It is a single category (Category 1), determined by corrosion-rate testing on steel and aluminum, and uses the corrosion pictogram (GHS05) with the hazard statement H290. It is a separate hazard from skin corrosion, even though both use GHS05.
Desensitized ExplosivesA physical-hazard class added by OSHA's 2024 HCS update (GHS Revision 7) for solid or liquid explosives that have been phlegmatized — wetted or diluted — to suppress their explosive properties for safe transport and storage. It has four categories based on the corrected burning rate, and uses the flame pictogram (GHS02), not the exploding-bomb.
Globally Harmonized System (GHS)An internationally agreed framework created by the United Nations (first adopted in 2003) that standardizes how chemical hazards are classified and communicated — using common hazard classes, pictograms, signal words (Danger / Warning), and coded hazard (H) and precautionary (P) statements on labels and safety data sheets. The US adopted GHS into law through OSHA's 2012 Hazard Communication Standard update.
Sources & verification
- 29 CFR 1910.1200 App B.15 (eCFR / OSHA.gov)
- OSHA — 1910.1200 Appendix B.15 (Organic Peroxides)
- OSHA — Hazard Communication (Physical Hazards)
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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