Skip to content

Approaching: Nov 20, 2026 — HCS 2024 Deadline. Get ready →

GHS / HazCom term · Glossary

GHS07 (Exclamation Mark)

Verified vs OSHA sources · 2026-10-05

The GHS hazard pictogram showing an exclamation mark. It flags the less-severe hazards: acute toxicity Category 4 (“harmful”), skin and eye irritation (Category 2), skin sensitization, respiratory tract irritation and narcotic effects (STOT single-exposure Category 3). The international GHS also assigns ozone-layer hazards to this symbol, but OSHA's Appendix C does not carry that class, so it never appears on a US workplace label. It is not used for the serious chronic hazards, which use the health-hazard pictogram (GHS08).

29 CFR 1910.1200 App C

Also known as: exclamation mark pictogram, irritant symbol

GHS07 (Exclamation Mark) at a glance

  • Covers acute toxicity Category 4 (“harmful”) — the mildest acute-tox tier.
  • Also: skin/eye irritation (Cat 2), skin sensitization (Cat 1), STOT-SE Cat 3.
  • The international GHS also puts ozone-layer hazards behind this symbol. OSHA did not adopt that class — it is an environmental hazard, outside OSHA's jurisdiction, for the same reason the GHS09 environment pictogram is not required.
  • Signal word is usually “Warning.”
  • NOT for the severe or chronic hazards (those use the skull GHS06 or health-hazard GHS08).

In plain English

The “be careful — this can hurt but probably won't kill you” symbol. It covers milder problems: harmful (not fatal) doses, rashes, eye/skin irritation, allergic skin reactions, and stuff that makes you drowsy or coughy.

What the source says, in summary

H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation.
OSHA HCS — hazard statements (App C)Summarized, not quoted: read the source for its operative wording.

In context

A classification or labeling concept from the UN Globally Harmonized System, adopted into US law through OSHA's Hazard Communication Standard (29 CFR 1910.1200) and its appendices.

29 CFR 1910.1200

Where this is written in OSHA's rules

Example

A household-strength cleaner classified for skin and eye irritation carries the exclamation-mark pictogram (GHS07) with the signal word “Warning” and H319, “Causes serious eye irritation.” A skin sensitizer like some epoxies uses the same GHS07 with H317, “May cause an allergic skin reaction.”

Why it matters

GHS07 is the “moderate” warning, and its danger is being taken too lightly — workers may skip PPE for an “irritant” that is actually a sensitizer, developing a lifelong allergy. Assigning GHS07 where the skull (GHS06) or health-hazard (GHS08) belongs understates a serious hazard and is a HazCom classification error under 1910.1200.

Exclamation mark (GHS07) vs. skull (GHS06) vs. health hazard (GHS08)

GHS07 is for mild, mostly reversible effects (“harmful,” irritation). The skull (GHS06) is for severe acute toxicity (“fatal”/“toxic,” Cat 1–3). The health-hazard silhouette (GHS08) is for serious chronic effects (cancer, organ damage). The category and severity decide which.

Hazards under the exclamation-mark pictogram (GHS07)

HazardH-code
Acute toxicity, Category 4 (harmful)H302 / H312 / H332
Skin irritation (Cat 2)H315
Serious eye irritation (Cat 2A)H319
Skin sensitization (Cat 1)H317
Respiratory irritation / narcotic (STOT-SE 3)H335 / H336

GHS07 (Exclamation Mark): frequently asked questions

What does the exclamation mark pictogram mean?
It signals moderate hazards: harmful (not fatal) acute toxicity Category 4, skin/eye irritation, skin sensitization, and respiratory irritation or drowsiness (STOT-SE Category 3). It does not cover ozone-layer hazards under OSHA's rule: the international GHS places those behind this symbol, but OSHA's Appendix C does not include the class at all. The signal word is usually “Warning.”
Is the exclamation mark less serious than the skull?
Yes. The skull (GHS06) is for severe acute toxicity (Categories 1–3, “fatal”/“toxic”). The exclamation mark (GHS07) is for the mildest tier (Category 4, “harmful”) and irritation-type effects.
Why isn't the exclamation mark used for cancer or organ damage?
Those serious, chronic health hazards use the health-hazard pictogram (GHS08). GHS07 is reserved for milder, generally reversible effects.

Related terms

Free tools for this

Governing OSHA standards

More GHS terms

Acute Toxicity

A GHS health-hazard class for the harmful effects that follow a single dose, several doses within 24 hours, or a 4-hour inhalation exposure. Chemicals are sorted into categories by route (oral, dermal, inhalation) using LD50/LC50 cut-offs — Category 1 is the most toxic. OSHA's HazCom standard uses Categories 1–4.

Aspiration Hazard

A GHS health-hazard class for chemicals that can be fatal if swallowed and then enter the airways — directly or by vomiting — causing chemical pneumonia or lung injury. Thin, low-viscosity hydrocarbons (gasoline, kerosene, lamp oil) are the classic example. It is Category 1, with the health-hazard pictogram (GHS08) and signal word “Danger.”

Carcinogenicity

A GHS health-hazard class for chemicals that cause cancer or increase its incidence. GHS (and OSHA's HazCom standard) sorts carcinogens into Category 1A (known human carcinogen), 1B (presumed, from animal evidence), and Category 2 (suspected). Carcinogens carry the health-hazard pictogram (GHS08) and a hazard statement such as H350 (“May cause cancer”).

Chemicals Under Pressure

A physical-hazard class added by OSHA's 2024 HCS update (aligning with GHS Revision 7) for liquids or solids pressurized with a gas, held in pressure receptacles other than aerosol dispensers and not classified as gases under pressure. It is categorized by the flammability of its contents and always carries the gas-cylinder pictogram (GHS04) for the pressure hazard.

Classification

The process of evaluating the available scientific evidence for a chemical against the GHS criteria to decide whether it is hazardous and, if so, the hazard class and category of each effect. Classification is the first step in HazCom — its result determines every label element (pictogram, signal word, hazard and precautionary statements) and SDS content.

Corrosive to Metals

A GHS physical-hazard class for chemicals that, by chemical action, will materially damage or even destroy metals. It is a single category (Category 1), determined by corrosion-rate testing on steel and aluminum, and uses the corrosion pictogram (GHS05) with the hazard statement H290. It is a separate hazard from skin corrosion, even though both use GHS05.

Desensitized Explosives

A physical-hazard class added by OSHA's 2024 HCS update (GHS Revision 7) for solid or liquid explosives that have been phlegmatized — wetted or diluted — to suppress their explosive properties for safe transport and storage. It has four categories based on the corrected burning rate, and uses the flame pictogram (GHS02), not the exploding-bomb.

Globally Harmonized System (GHS)

An internationally agreed framework created by the United Nations (first adopted in 2003) that standardizes how chemical hazards are classified and communicated — using common hazard classes, pictograms, signal words (Danger / Warning), and coded hazard (H) and precautionary (P) statements on labels and safety data sheets. The US adopted GHS into law through OSHA's 2012 Hazard Communication Standard update.

Sources & verification

Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.

Put GHS07 (Exclamation Mark) into practice

Don't just read the definition — apply it. Use the free GHS Label Generator to put real numbers behind GHS07 (Exclamation Mark) for your jobsite.

Get the Binder in Order Before the Inspector Arrives. Are You Ready?

OSHA does not give advance notice of inspections (29 CFR 1903.6). Get the binder in order before the opening conference, not during it.

Serious Violation

$16,550

per violation (max)

HazComFast Pro

$199/mo

10 jobsites, unlimited chemicals, unlimited workers

New sign-ups are paused. The free tools below need no account, and customers can log in as usual.

Your account keeps working as usual. Cancel anytime.