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General safety term · Glossary

NFPA 704 Diamond

The NFPA “fire diamond” — a four-quadrant placard that gives emergency responders an at-a-glance sense of a material's hazards: blue (health), red (flammability), and yellow (instability/reactivity) each rated 0 (minimal) to 4 (severe), plus a white quadrant for special hazards (like OX for oxidizer or W̶ for water-reactive). It's for responders at fixed installations — a different system from GHS labels.

Also known as: fire diamond, NFPA hazard diamond, 704 placard

NFPA 704 Diamond at a glance

  • Four quadrants: blue = health, red = flammability, yellow = instability/reactivity, white = special.
  • Blue/red/yellow are rated 0 (minimal) to 4 (severe).
  • White holds symbols, not numbers: OX (oxidizer), W̶ (water-reactive), SA (simple asphyxiant).
  • Designed for EMERGENCY RESPONDERS at fixed sites — not a substitute for GHS labels.

In plain English

The diamond-shaped hazard sign you see on tanks and building doors — four colored boxes with numbers 0 to 4. It tells firefighters in seconds how dangerous the contents are to their health, how easily it burns, how reactive it is, and any special warning.

What the source says, in summary

NFPA 704 provides a readily recognized, easily understood system of markings that gives emergency responders a general sense of the health, flammability, and instability hazards of a material, rated on a scale of 0 (minimal hazard) to 4 (severe hazard).
NFPA 704Summarized, not quoted: read the source for its operative wording.

In context

An industrial-hygiene, exposure-control, or program-management concept that applies across OSHA standards and workplaces.

29 CFR 1910 / 1926

Example

A tank of concentrated nitric acid might show NFPA 704 as blue 3 (serious health hazard), red 0 (won't burn), yellow 1 (normally stable), and white OX (oxidizer) — telling a responder at a glance it's corrosive, non-flammable, but an oxidizer to keep away from fuels.

Why it matters

The fire diamond is what a firefighter reads from a distance before entering a building or approaching a spill, so getting the ratings right can shape their whole response. But it's a responder tool, not worker hazard communication — relying on an NFPA diamond instead of a GHS label for employees is a HazCom compliance gap.

NFPA 704 vs. GHS labels

NFPA 704 (and the similar HMIS bars) rate hazards 0–4 for emergency responders at fixed installations. GHS labels (pictograms, signal word, hazard statements) are OSHA's worker hazard communication on containers. They look similar but serve different audiences — and the NFPA diamond does not satisfy the HazCom labeling requirement.

The NFPA 704 fire diamond

Quadrant (color)HazardScale
Blue (left)Health0 (minimal) – 4 (deadly)
Red (top)Flammability0 – 4
Yellow (right)Instability / reactivity0 – 4
White (bottom)Special (OX, W̶, SA)Symbols, not a number

NFPA 704 Diamond: frequently asked questions

What do the NFPA 704 colors mean?
Blue is health hazard, red is flammability, yellow is instability/reactivity — each rated 0 (minimal) to 4 (severe) — and white is for special hazards such as OX (oxidizer) or W̶ (reacts with water).
What do the NFPA numbers 0–4 mean?
They rate severity: 0 is minimal hazard and 4 is severe. For example, red 4 means an extremely flammable material; blue 4 means a material that can be lethal on short exposure.
Is NFPA 704 the same as a GHS label?
No. NFPA 704 is a responder-oriented hazard rating for fixed installations. GHS labels are OSHA's worker hazard communication on containers. The fire diamond does not replace the required GHS label.

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Biological Exposure Index (BEI)

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California Proposition 65

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CAS Number

A unique numerical identifier assigned by the Chemical Abstracts Service (a division of the American Chemical Society) to every distinct chemical substance. It has the format of up to seven digits, a dash, two digits, a dash, and a final check digit (e.g., 67-64-1 for acetone). Because chemical names vary, the CAS number is the unambiguous global key used on SDSs, inventories, and regulations.

Ceiling Limit

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Sources & verification

Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.

Put NFPA 704 Diamond into practice

Don't just read the definition — apply it. Use the free Chemical Compatibility Matrix to put real numbers behind NFPA 704 Diamond for your jobsite.

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