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General safety term · Glossary

Hazardous Waste

Verified vs OSHA sources · 2026-10-05

A solid waste that is dangerous to human health or the environment and is regulated under the federal Resource Conservation and Recovery Act (RCRA), administered by the EPA (40 CFR Part 261). A waste is hazardous if it either exhibits one of four CHARACTERISTICS — ignitability (D001), corrosivity (D002), reactivity (D003), or toxicity (D004–D043, via the TCLP test) — or appears on one of the LISTED-waste lists: F (non-specific source), K (specific source), or P and U (discarded commercial chemical products, with P being acutely hazardous). Worker protection during hazardous-waste operations and emergency response is governed separately by OSHA's HAZWOPER standard (29 CFR 1910.120).

29 CFR 1910.120

Also known as: RCRA hazardous waste, regulated waste, hazwaste

Hazardous Waste at a glance

  • Regulated under RCRA (Resource Conservation and Recovery Act), administered by the EPA — a different framework from OSHA workplace standards.
  • Four characteristic wastes: Ignitability (D001) — liquids with a flash point below 140°F (60°C); Corrosivity (D002) — aqueous wastes with pH ≤ 2 or ≥ 12.5; Reactivity (D003) — unstable, reacts violently, or generates toxic gases; Toxicity (D004–D043) — leaches harmful concentrations by the TCLP test.
  • Listed wastes: F-list (non-specific source, e.g., spent solvents), K-list (specific industry sources), P-list (acutely hazardous discarded chemicals), U-list (other discarded commercial chemical products).
  • P-listed wastes are 'acutely hazardous' and carry the strictest handling and small-quantity thresholds.
  • Worker safety during hazardous-waste site cleanup, TSD operations, and emergency response is covered by OSHA HAZWOPER (29 CFR 1910.120) — not RCRA.
  • SDS Section 13 (Disposal Considerations) provides waste-handling guidance but does not itself determine RCRA classification.
  • CERCLA (Superfund) addresses cleanup of past hazardous-substance releases; RCRA governs waste that is generated, transported, treated, stored, and disposed of today.

In plain English

Leftover material that's dangerous enough that you can't just throw it in the trash — it can catch fire, burn skin, react violently, or poison groundwater. The EPA decides what counts as hazardous waste (under RCRA), either by testing it against four danger 'characteristics' or by matching it to published lists of known hazardous wastes. Separately, OSHA's HAZWOPER rules protect the workers who handle it.

What the source says, in summary

A solid waste... is a hazardous waste if it exhibits any of the characteristics of ignitability, corrosivity, reactivity, or toxicity [as defined by 40 CFR 261.21–261.24].
40 CFR 261.20–261.24 — Characteristics of hazardous wasteSummarized, not quoted: read the source for its operative wording.

In context

An industrial-hygiene, exposure-control, or program-management concept that applies across OSHA standards and workplaces.

29 CFR 1910 / 1926

Where this is written in OSHA's rules

Example

A shop generates a drum of spent mineral-spirits solvent from parts cleaning. Two independent tests can make it a hazardous waste: it may be an F-listed waste (F005, a listed spent solvent) AND exhibit the ignitability characteristic (D001) because its flash point is below 140°F. Either basis alone makes it RCRA hazardous waste, requiring proper labeling, a manifest for off-site shipment to a permitted TSD facility, and compliance with generator accumulation limits. Workers handling it are protected under OSHA HAZWOPER and informed by the product's SDS Section 13.

Why it matters

Misclassifying or improperly disposing of hazardous waste exposes a business to EPA enforcement under RCRA — with substantial per-day civil penalties — as well as environmental liability and, for the workers who handle it, serious health and safety hazards addressed by OSHA HAZWOPER. Because a single waste stream can be hazardous under multiple bases (a characteristic and a listing at the same time), generators must evaluate each stream carefully rather than assume a single test settles the question.

RCRA (EPA) vs. HAZWOPER (OSHA) vs. CERCLA

Three different regimes touch hazardous waste, and they are frequently conflated. RCRA (EPA, 40 CFR Part 261) defines what IS a hazardous waste and regulates its cradle-to-grave management — generation, transport, treatment, storage, and disposal. HAZWOPER (OSHA, 29 CFR 1910.120) protects WORKERS engaged in hazardous-waste operations and emergency response. CERCLA/Superfund addresses CLEANUP and liability for past releases of hazardous substances into the environment. RCRA classifies today's waste; CERCLA cleans up yesterday's contamination; HAZWOPER keeps the workers safe throughout.

How a Waste Becomes RCRA Hazardous (40 CFR Part 261)

BasisCode(s)Criterion
IgnitabilityD001Flash point below 140°F (60°C), or ignitable compressed gas/oxidizer
CorrosivityD002Aqueous pH ≤ 2 or ≥ 12.5, or corrodes steel
ReactivityD003Unstable, reacts with water, or generates toxic gases/detonates
ToxicityD004–D043Leaches harmful concentrations by the TCLP test
Listed — F/KF, KFrom non-specific (F) or specific-industry (K) sources
Listed — P/UP, UDiscarded commercial chemicals (P = acutely hazardous)

Hazardous Waste: frequently asked questions

Who regulates hazardous waste — OSHA or EPA?
Primarily the EPA, under the Resource Conservation and Recovery Act (RCRA, 40 CFR Part 261), which defines hazardous waste and regulates its cradle-to-grave management. OSHA's role is worker protection: its HAZWOPER standard (29 CFR 1910.120) protects employees engaged in hazardous-waste operations, treatment/storage/disposal work, and emergency response. A generator typically must comply with both — RCRA for the waste itself and HAZWOPER for the workers who handle it.
What are the four characteristics that make a waste hazardous?
Ignitability (D001 — flash point below 140°F/60°C, or an ignitable compressed gas/oxidizer); corrosivity (D002 — aqueous pH of 2 or less, or 12.5 or greater, or the ability to corrode steel); reactivity (D003 — unstable, reacts violently or with water, or generates toxic gases); and toxicity (D004–D043 — leaches harmful concentrations of specified contaminants as measured by the Toxicity Characteristic Leaching Procedure, or TCLP). Exhibiting any one characteristic makes the waste hazardous.
What is the difference between characteristic and listed hazardous waste?
A CHARACTERISTIC hazardous waste is hazardous because it exhibits ignitability, corrosivity, reactivity, or toxicity when tested. A LISTED hazardous waste is hazardous because it appears on an EPA list regardless of a test result: the F-list (wastes from non-specific sources like spent solvents), K-list (wastes from specific industries), P-list (acutely hazardous discarded commercial chemicals), and U-list (other discarded commercial chemical products). A single waste can be both listed and characteristic at the same time.

Related terms

More General Safety terms

Arc Flash

An arc flash is the sudden release of thermal energy from an electrical arc fault — a short circuit that jumps through the air between energized parts. The arc can reach temperatures over 35,000°F (nearly four times the surface of the sun), causing severe burns, igniting clothing, and driving an explosive pressure wave known as the arc blast. OSHA sets no single “arc-flash standard”: the analysis method — the arc-flash boundary, incident energy, and arc-rated PPE — comes from the NFPA 70E consensus standard, which OSHA enforces through its electrical-PPE rules (29 CFR 1910.335, 1910.269) and the General Duty Clause.

Action Level

An airborne concentration of a substance — typically half the PEL — at which certain provisions of an OSHA standard kick in (such as exposure monitoring, training, and medical surveillance), even though it is below the legal exposure limit. For respirable crystalline silica the action level is 25 µg/m³ as an 8-hour TWA, half the 50 µg/m³ PEL.

Administrative Controls

Changes to how and when work is done — job rotation, scheduling, safe work practices, housekeeping, training, and signage — that reduce a worker's exposure without altering the hazard itself. They are the fourth tier of the hierarchy of controls, below engineering controls and above PPE.

Biological Exposure Index (BEI)

An ACGIH guidance value for interpreting biological monitoring results — the concentration of a chemical (or its metabolite) measured in a worker's blood, urine, or exhaled breath. A BEI represents the level most likely found in a healthy worker whose inhalation exposure was at the TLV, so it measures the dose the body actually absorbed, not just what's in the air.

California Proposition 65

California's Safe Drinking Water and Toxic Enforcement Act of 1986. It requires businesses to warn Californians before exposing them to any of the ~900+ listed chemicals known to the state to cause cancer, birth defects, or other reproductive harm, and prohibits discharging those chemicals into drinking-water sources. It's a California law, but it reaches nearly any product sold there.

CAS Number

A unique numerical identifier assigned by the Chemical Abstracts Service (a division of the American Chemical Society) to every distinct chemical substance. It has the format of up to seven digits, a dash, two digits, a dash, and a final check digit (e.g., 67-64-1 for acetone). Because chemical names vary, the CAS number is the unambiguous global key used on SDSs, inventories, and regulations.

Ceiling Limit

An exposure limit that must not be exceeded at any instant during the workday — the strictest type of OSHA exposure limit. In OSHA's Z-tables it is marked with a “C” before the value. Unlike an 8-hour TWA (an average) or a 15-minute STEL, a ceiling applies to a single moment.

Chemical Compatibility

Whether two or more chemicals can be safely stored or used near each other without reacting dangerously — releasing heat, toxic gas, or fire. Incompatible chemicals must be physically separated (segregated) in storage. Each chemical's incompatibilities are listed in Section 10 of its SDS, and compatibility drives storage layout and spill response.

Sources & verification

Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.

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