General safety term · Glossary
UN Number
A four-digit identification number assigned by the United Nations to hazardous substances and articles for transport (for example, UN1203 for gasoline). It's used worldwide on shipping papers, placards, and packaging to identify what's being transported, and it appears in Section 14 of the SDS alongside the proper shipping name and hazard class.
Also known as: UN ID, UN/NA number
On this page
UN Number at a glance
- A four-digit code (UN0004–UN3600 range) for transport identification.
- Used on placards, packaging, and shipping papers worldwide.
- Appears in Section 14 of the SDS with the proper shipping name and class.
- Different from the CAS number, which identifies the chemical for science, not transport.
In plain English
The four-digit code (like UN1203) that identifies a hazardous material for shipping. It's on the placard of the tanker truck next to you on the highway, and it tells responders exactly what's inside.
What the source says, in summary
The UN number is a four-digit number assigned by the United Nations Committee of Experts to identify a substance or article of dangerous goods for the purpose of transport; it appears on shipping documents, packaging, and placards.
In context
An industrial-hygiene, exposure-control, or program-management concept that applies across OSHA standards and workplaces.
Example
A tanker placarded “1203” is carrying gasoline (UN1203). A responder can look up UN1203 to find its shipping name, hazard class (3, flammable liquid), and emergency response guidance — all keyed off that one four-digit number found in SDS Section 14.
Why it matters
The UN number is the universal key for emergency response and legal shipping — the placard on a truck, the entry in a response guide, and the shipping paper all reference it. A wrong or missing UN number means mis-placarded, mis-shipped hazardous cargo, a DOT violation, and responders working blind.
UN number vs. CAS number
A UN number identifies a material for TRANSPORT (shipping, placarding, emergency response) and can cover a category (UN1993 = “flammable liquid, n.o.s.”). A CAS number identifies a specific CHEMICAL substance for scientific reference. A product has a CAS number for its ingredient and a UN number for shipping.
Example UN numbers (SDS Section 14)
| UN number | Substance / entry |
|---|---|
| UN1203 | Gasoline (petrol) |
| UN1830 | Sulfuric acid |
| UN1017 | Chlorine |
| UN1993 | Flammable liquid, n.o.s. (not otherwise specified) |
UN Number: frequently asked questions
- What is a UN number?
- A four-digit number assigned by the United Nations to identify a hazardous material for transport. It appears on placards, packaging, and shipping papers, and in Section 14 of the SDS — for example, UN1203 for gasoline.
- What's the difference between a UN number and a CAS number?
- A UN number identifies a material for transport and emergency response (and can cover a whole category). A CAS number uniquely identifies a specific chemical substance for scientific and regulatory reference. They serve different purposes.
- Where is the UN number on an SDS?
- In Section 14 (Transport information), alongside the proper shipping name, transport hazard class, and packing group.
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Sources & verification
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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