Safety Data Sheet term · Glossary
Material Safety Data Sheet (MSDS)
Verified vs OSHA sources · 2026-10-05
The legacy hazard-communication document that preceded today's Safety Data Sheet (SDS). Before OSHA aligned the Hazard Communication Standard with the Globally Harmonized System (GHS) in 2012, MSDSs had no mandated section order or format, so information appeared in inconsistent places from one manufacturer to the next. The 2012 HazCom update replaced the MSDS with the standardized 16-section SDS. Under the transition schedule, compliance with all modified provisions — including GHS-aligned 16-section SDSs — was due June 1, 2015, with the phase-in closing June 1, 2016. The term 'MSDS' is now obsolete, though it persists in older files and everyday speech.
Also known as: MSDS, material safety data sheet, legacy data sheet
On this page
Material Safety Data Sheet (MSDS) at a glance
- MSDS = the pre-2012 predecessor of the SDS; it had no standardized section order or format.
- The 2012 HazCom update (aligning with GHS) replaced the MSDS with the 16-section SDS.
- GHS-aligned 16-section SDSs were required from June 1, 2015; the phase-in closed June 1, 2016.
- The 16-section SDS format puts the same information in the same place every time (identification, hazards, composition, first aid, firefighting, and so on).
- 'MSDS' is now obsolete terminology; the correct current term is 'Safety Data Sheet (SDS).'
- Sections 12–15 of the SDS (ecological, disposal, transport, regulatory) are included for GHS harmonization but are not enforced by OSHA, which lacks jurisdiction over those areas.
In plain English
The old version of the safety data sheet. Before 2012, every manufacturer wrote its 'MSDS' in its own layout, so finding the first-aid or fire-fighting information meant hunting around a different document each time. OSHA fixed that by adopting the international 16-section SDS format. If you still see 'MSDS' on a document, it's out of date — it should have been replaced with a GHS-aligned SDS by June 1, 2015.
What the rule says
“The chemical manufacturer or importer shall ensure that the safety data sheet is in English (although the employer may maintain copies in other languages as well), and includes at least the following section numbers and headings, and associated information under each heading, in the order listed (see appendix D to this section, for the specific content of each section of the safety data sheet):”
In context
A concept tied to the 16-section Safety Data Sheet required for every hazardous chemical under OSHA's Hazard Communication Standard, 29 CFR 1910.1200(g).
Where this is written in OSHA's rules
- 29 CFR 1910.1200(g)Read on eCFR / OSHA.gov
- 29 CFR 1910.1200(g)(2)Read on eCFR / OSHA.gov
Example
A maintenance manager opens a binder from 2010 and finds a two-page 'Material Safety Data Sheet' for a degreaser, with fire and first-aid information buried in narrative paragraphs in no fixed order. An MSDS received before June 1, 2015 is still compliant unless the supplier has provided a new SDS that was not kept (OSHA letter of interpretation, July 27, 2015). The manager can request the current 16-section SDS from the manufacturer or supplier, who must provide it (1910.1200(g)(6)(iv)), and there firefighting measures are always Section 5 and first-aid measures are always Section 4 — regardless of who made the chemical.
Why it matters
Retaining obsolete MSDSs instead of current SDSs is a common HazCom compliance gap that OSHA cites during inspections. Beyond the citation risk, the inconsistent MSDS format cost workers precious time in an emergency — the whole point of the 16-section SDS is that responders can find first aid, firefighting, and spill information instantly, in the same location on every sheet. Understanding that 'MSDS' signals an outdated document helps employers audit and replace stale files.
MSDS vs. SDS — is there any difference?
They serve the same purpose — communicating chemical hazards — but they are not interchangeable for compliance. The MSDS was the older, format-free document; the SDS is the current, mandatory 16-section format adopted with the 2012 GHS-aligned HazCom Standard. Since June 1, 2015, only GHS-aligned SDSs satisfy OSHA. If a document is labeled 'MSDS' or lacks the standardized 16 sections in order, it is a legacy document and should be replaced. Saying 'MSDS' when you mean 'SDS' is common in the field, but the underlying documents are legally distinct.
MSDS (legacy) vs. SDS (current)
| Attribute | MSDS (pre-2012) | SDS (2012 GHS-aligned) |
|---|---|---|
| Format | No mandated order or format | Standardized 16 sections in fixed order |
| Basis | Pre-GHS HazCom | GHS-aligned HazCom (2012) |
| Compliance status | Superseded from June 1, 2015 | Current required document |
| Finding information | Varies by manufacturer | Same section number every time |
Material Safety Data Sheet (MSDS): frequently asked questions
- Are MSDSs still valid, or must they be replaced with SDSs?
- They must be replaced. Under the 2012 GHS-aligned Hazard Communication Standard, GHS-formatted 16-section Safety Data Sheets were required from June 1, 2015, with the phase-in closing June 1, 2016. A document still in the old MSDS format is obsolete and does not satisfy OSHA. Employers should audit their files and obtain current SDSs from manufacturers or suppliers for any legacy MSDS.
- Why did OSHA replace the MSDS with the 16-section SDS?
- The old MSDS had no mandated format, so the same information appeared in different places on each manufacturer's sheet — costing responders time in an emergency. By adopting the Globally Harmonized System (GHS) in the 2012 HazCom update, OSHA required a fixed 16-section order so that identification, hazards, first aid, firefighting, handling, and other information always appear in the same numbered section, regardless of who made the chemical. This standardization is the core reason the MSDS was retired in favor of the SDS.
- Why does the term 'MSDS' still show up if it's obsolete?
- 'MSDS' persists in older archived files created before the transition, in casual speech and habit, and in some non-U.S. jurisdictions with different timelines. In the U.S., however, the compliant document has been the 16-section SDS since the 2012 HazCom update, required from June 1, 2015 with the phase-in closing June 1, 2016. When you encounter 'MSDS,' treat it as a signal to verify you have the current SDS.
Related terms
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Governing OSHA standards
More SDS terms
A standardized 16-section document the chemical manufacturer, importer, or distributor must provide for every hazardous chemical, detailing its hazards, safe handling, storage, exposure controls, first aid, and emergency information. Its content and order are set by 29 CFR 1910.1200(g) and Appendix D; it replaced the unstandardized MSDS under GHS alignment.
Readily AccessibleThe OSHA requirement that safety data sheets be readily accessible to employees during each work shift, in their work areas (29 CFR 1910.1200(g)(8); adopted for construction by 1926.59). “Readily accessible” means without barriers or unreasonable delay — electronic access is allowed, but only with reliable backup for power or system failures and no obstacle between the worker and the SDS.
Section 1: IdentificationThe first section of a Safety Data Sheet. It identifies the chemical and who's responsible for it: the product identifier (matching the label), recommended use and restrictions, the manufacturer/importer's name, address, and phone, and — critically — an emergency phone number. It's the section a responder reads first to confirm they have the right SDS.
Section 2: Hazard IdentificationThe SDS section that states what's dangerous about the chemical: its GHS hazard classification (each hazard class and category), all the required label elements (pictograms, signal word, hazard statements, precautionary statements), and any hazards not otherwise classified (HNOC). It's the fastest read for “how could this hurt me?”
Section 3: Composition / Information on IngredientsThe SDS section that discloses what the chemical is made of: the chemical name, common names/synonyms, CAS number, and concentration (or concentration range) of the substance or of each hazardous ingredient in a mixture. Any ingredient that contributes to a classified hazard must be listed, subject to limited trade-secret protection.
Section 4: First-Aid MeasuresThe SDS section that tells you what to do if someone is exposed. It gives first-aid instructions broken out by route of exposure — inhalation, skin, eye, and ingestion — plus the most important symptoms (immediate and delayed) and any indication of the need for immediate medical attention or special treatment. It's the section to open in a medical emergency.
Section 5: Fire-Fighting MeasuresThe SDS section written for anyone fighting a fire involving the chemical. It lists suitable and unsuitable extinguishing media, the specific hazards the chemical creates in a fire (toxic combustion products, explosion risk, reactivity), and the special protective equipment and precautions firefighters need. It's a key reference for the fire department's pre-planning.
Section 6: Accidental Release MeasuresThe SDS section that tells you how to handle a spill or leak. It covers personal precautions, protective equipment, and emergency procedures (protecting people first), environmental precautions (keeping it out of drains and waterways), and the methods and materials for containment and cleanup. It's the spill-response playbook for the chemical.
Sources & verification
- 29 CFR 1910.1200(g) (eCFR / OSHA.gov)
- 29 CFR 1910.1200(g)(2) (eCFR / OSHA.gov)
- OSHA — Hazard Communication (SDS)
- OSHA — Brief: Hazard Communication Safety Data Sheets
Reviewed by HazComFast against eCFR, OSHA.gov, NIOSH, and the Federal Register. Last reviewed 2026-10-05. This glossary is general information, not legal advice; OSHA State-Plan states (e.g. California, Michigan) may adopt stricter requirements.
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