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Metals · CAS Database

Mercury

Mercury (CAS 7439-97-6) — Liquid metal for instruments. Get the SDS and OSHA HazCom guidance you need to store, label, and handle it safely on the job site.

Verified vs OSHA sources · October 5, 2026

CAS Registry Number CAS 7439-97-6 · also known as Hg, Quicksilver, Hydrargyrum

Overview

Liquid metal for instruments

Synonyms:HgQuicksilverHydrargyrum

Mercury on the job site

Mercury isn't bought for construction — it's released during demolition and renovation from the legacy equipment it hides in: old thermostats, fluorescent and HID lamps, tilt switches, gauges, manometers, and thermometers. Break one and you get liquid mercury that slowly evaporates into an odorless, colorless vapor; in a warm, enclosed room that vapor reaches harmful levels, and elemental mercury vapor damages the nervous system and kidneys.

The dangerous instinct is to “clean it up” with a shop vacuum or broom — a vacuum atomizes mercury and blows the vapor throughout the space, making it far worse. Instead, isolate and ventilate the area, keep people out, and use proper mercury spill procedures/kit (or a qualified contractor) for anything beyond a trace. During demolition, identify and remove mercury-containing devices before they're broken, and handle spent lamps as universal/hazardous waste rather than crushing them on site.

Key takeaways

  • Mercury vapor from broken lamps/thermostats is odorless and harms the nervous system and kidneys.
  • Never vacuum or sweep a spill — it atomizes mercury and spreads the vapor; isolate, ventilate, use a spill kit.
  • Identify and remove mercury devices before demolition; manage spent lamps as hazardous waste, don't crush them.

Field guidance for planning and training — not a substitute for the manufacturer Safety Data Sheet, which controls the exposure limit, PPE, and handling for your specific product.

OSHA Exposure Limits

OSHA permissible exposure limit (PEL) and secondary limit for Mercury on a US construction site. Where a substance-specific 1926 standard applies, its codified limit is shown; otherwise the figure comes from Table 1 to 29 CFR 1926.55, the construction air-contaminants table. Where 1926.55 does not list the substance, the Safety Data Sheet (Section 8) controls.

LimitValueBasis / citation
OSHA PEL (ceiling)(C) 0.1 mg/m³29 CFR 1910.1000 Table Z-2
Action levelSee SDS / standardNot all substances define an action level
Averaging periodceilingA ceiling is never averaged: it must not be exceeded at any moment of the shift. Compare with ACGIH TLV / NIOSH REL — often more protective than the OSHA PEL

This limit is a ceiling. Exposure must at no time exceed it. Where instantaneous monitoring is not feasible, 29 CFR 1926.55(a)(1) lets the employer assess the ceiling as a 15-minute time-weighted average — one that still may not be exceeded at any time during the working day.

This is the general-industry figure. Construction air contaminants are listed separately in Table 1 to 29 CFR 1926.55, and on 33 substances the two differ — sometimes by a wide margin. Where they differ, the construction value governs work on a jobsite.

Many OSHA PELs date to 1971 and may be less protective than current ACGIH/NIOSH values; always check the manufacturer SDS (Section 8) for the controlling limit and engineering-control guidance. Not legal advice.

GHS Classification

The manufacturer or importer of Mercury (CAS 7439-97-6) classifies its hazards (29 CFR 1910.1200(d)(1)). You'll find them in Section 2, Hazard(s) identification, of the manufacturer's Safety Data Sheet (29 CFR 1910.1200(g)(2)(ii)).

Physical Properties

Molecular FormulaHg
Molecular Weight200.59
Boiling Point675 °F at 760 mmHg (USCG, 1999)
Melting Point-38 °F (USCG, 1999)
Density13.55 at 68 °F (USCG, 1999) - Denser than water; will sink
Vapor Pressure0.0012 mmHg (NIOSH, 2024)
SolubilityInsoluble (NIOSH, 2024)

Where Mercury shows up on the job

Trades that commonly handle Mercury, each with an OSHA HazCom guide built for the chemicals and tasks on that kind of site:

OSHA & HazCom Compliance Requirements

For construction work, Hazard Communication is governed by 29 CFR 1926.59 (adopts 29 CFR 1910.1200). Employers who use Mercury must:

  • •Maintain an accessible SDS for Mercury (readily accessible during each work shift, 29 CFR 1910.1200(g)(8))
  • •Label all containers with GHS-compliant labels (29 CFR 1910.1200(f)(1) shipped / 29 CFR 1910.1200(f)(6) workplace)
  • •Include it in the workplace chemical inventory
  • •Train employees on hazards before initial assignment
  • •Retain employee exposure and medical records per 29 CFR 1910.1020 — 30-year retention applies to exposure/medical records, not to SDSs generically

HazCom (1910.1200 / construction 1926.59) covers labels, SDSs, and training only — it does not impose chemical storage segregation. Flammable & combustible liquid storage for construction is 29 CFR 1926.152; segregation of incompatibles is planned from SDS Sections 7 and 10. Not legal advice; state-plan states may have stricter rules.

Handling & Secondary-Container Labeling

When you transfer Mercury into a workplace (secondary) container, OSHA gives two compliant options under 29 CFR 1910.1200(f)(6):

  • •(f)(6)(i): full GHS label elements (as on the shipped container)
  • •(f)(6)(ii): product identifier + words/pictures/symbols (or combination) that provide AT LEAST general information on the hazards

There is no volume/size cutoff for secondary containers — the ≤100 ml / ≤3 ml accommodations (29 CFR 1910.1200(f)(12) (added by the HCS 2024 final rule)) apply only to the manufacturer's shipped container. A portable container filled for the immediate use of the worker who fills it needs no label (29 CFR 1910.1200(f)(8)).

GHS Hazard Classification under OSHA HCS

OSHA's Hazard Communication Standard adopts the GHS (primarily GHS Revision 7 (HCS 2024)). It requires 8 hazard pictograms (Appendix C, Figure C.1). The Environment pictogram (GHS09) is not required by OSHA — Not in App C; outside OSHA jurisdiction; voluntary.

The 8 OSHA-required pictograms:

FlameFlame Over CircleExclamation MarkExploding BombCorrosionGas CylinderHealth HazardSkull and Crossbones

For flammable liquids, OSHA classifies by flash point and boiling point (App B.6.1 / 1910.106(a)):

  • •Category 1: FP < 73.4°F AND BP <= 95°F
  • •Category 2: FP < 73.4°F AND BP > 95°F
  • •Category 3: FP >= 73.4°F AND <= 140°F
  • •Category 4: FP > 140°F AND <= 199.4°F

The specific GHS classification of Mercury comes from its Safety Data Sheet (Section 2). Use the live classification panel above and the manufacturer SDS to confirm pictograms and categories.

HCS 2024 Update Deadlines

Under the Hazard Communication Standard 2024 update (aligned primarily GHS Revision 7):

  • •May 19, 2026 — manufacturers, importers, and distributors update substance labels & SDSs (1910.1200(j)(2)(i))
  • •November 20, 2026 — employers update workplace labeling, the written program & training (1910.1200(j)(2)(ii))

During the interim, parts may comply with the 2012 HCS, the 2024 HCS, or both.

Quick Actions

Put Mercury on your written inventory, print the workplace label your containers need, and keep your supplier’s sheet reachable on the jobsite.

The safety data sheet for your product comes from the supplier who sold it to you — no public registry can provide it. For the underlying chemistry, the public record is on PubChem.

Where this fits in your HazCom program

  • SDS management — collecting the sheet, keeping it current, and making it readable during each work shift.
  • GHS labels & workplace labeling — what has to appear on the shipped container, and what a secondary container needs instead.

Frequently Asked Questions

What is Mercury (CAS 7439-97-6)?

Liquid metal for instruments

What are the OSHA HazCom requirements for Mercury on a construction site?

For construction work, Hazard Communication is governed by 29 CFR 1926.59 (adopts 29 CFR 1910.1200). Employers who use Mercury must maintain an accessible Safety Data Sheet (SDS), label containers with GHS-compliant labels, include the chemical in the workplace chemical inventory, and train workers on its hazards before initial assignment.

What is the OSHA permissible exposure limit (PEL) for Mercury?

OSHA's permissible exposure limit for Mercury is (C) 0.1 mg/m³ (ceiling), per 29 CFR 1910.1000 Table Z-2. That figure is the GENERAL-INDUSTRY limit; construction air contaminants are listed separately at 29 CFR 1926.55 Table 1, and where the two differ the construction value governs work on a jobsite. Where the ACGIH TLV or NIOSH REL is more protective, follow the lower value, and confirm the limit for your specific task against Section 8 of the manufacturer Safety Data Sheet.

When does the updated HCS 2024 labeling apply to Mercury?

Under the Hazard Communication Standard 2024 update (aligned primarily GHS Revision 7), chemical manufacturers, importers, and distributors must update substance labels and SDSs by May 19, 2026, and employers must update workplace labeling, the written program, and training for substances by November 20, 2026. During the interim, parties may comply with the 2012 HCS, the 2024 HCS, or both.

How do I label a secondary (workplace) container of Mercury?

Under 29 CFR 1910.1200(f)(6) you have two options: (i) the full GHS label elements as on the shipped container, or (ii) the product identifier plus words, pictures, symbols, or a combination that provide at least general hazard information. There is no volume/size cutoff for secondary containers. A portable container filled for the immediate use of the worker who fills it does not require a label (29 CFR 1910.1200(f)(8)).

How long must SDS and exposure records for Mercury be kept?

Under 29 CFR 1910.1020, 30-year retention applies to employee exposure and medical records (medical records: duration of employment plus 30 years) — not to SDSs generically. Where an SDS is not retained, a record of the chemical's identity, where it was used, and when must be kept for at least 30 years.

Where can I find the SDS for Mercury?

Under 29 CFR 1910.1200(g)(6) and (g)(7), the manufacturer, importer or distributor that sold you Mercury must send its Safety Data Sheet with the first shipment, and again with the first shipment after the sheet is updated. HazComFast keeps the sheets you collect in one inventory per jobsite, searchable by product, manufacturer or CAS number, and your jobsite's SDS load onto the phone on their own.

Regulatory data on this page is sourced from HazComFast's verified regulatory module (29 CFR 1926.59 / 1910.1200 and substance-specific 1926 standards), last verified October 5, 2026 against eCFR, OSHA.gov, and the Federal Register. Physical-property data comes from PubChem. Confirm it against the manufacturer Safety Data Sheet. This page is informational and is not legal advice.

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