What 29 CFR 1910.1000 requires (plain English)
29 CFR 1910.1000 is OSHA's master air-contaminant standard for general industry: the tables of permissible exposure limits (PELs) that apply to hundreds of chemicals that do not have their own substance-specific standard. It is the default exposure rule: an employee's exposure to any substance listed in Tables Z-1, Z-2, or Z-3 must be limited in accordance with the standard. When there is no dedicated standard (as there is for lead, silica, benzene, or asbestos), 1910.1000 governs.
The standard uses three kinds of limits. Most substances have an 8-hour time-weighted average (TWA): the average airborne concentration a worker may be exposed to over an 8-hour shift. Some substances (marked with a "C" in Table Z-1, or listed in Table Z-2) have an acceptable ceiling concentration that must never be exceeded, sometimes with an acceptable maximum peak allowed for a short, specified duration. Table Z-3 covers mineral dusts. Exposure is assessed by air sampling and compared against the applicable TWA or ceiling.
Two principles are essential. First, the hierarchy of controls applies by regulation: to achieve compliance, feasible administrative or engineering controls must be determined and implemented FIRST, and respirators are permitted only while those controls are being installed, when they are not feasible, or in emergencies. Second, and critically, most of these PELs were adopted in 1971 from 1968 ACGIH Threshold Limit Values and have not been updated, so many are widely regarded as outdated and under-protective. OSHA itself, NIOSH, and ACGIH recommend that employers control exposures below the PEL where more protective limits (such as NIOSH RELs or current ACGIH TLVs) exist. 'Below the 1910.1000 PEL' is the legal floor, not a guarantee of safety.